It may be good to note that PHP does not allow arbitrary session ids. The session id validation in PHP source is defined in ext/session/session.c in the function php_session_valid_key:

https://github.com/php/php-src/blob/master/ext/session/session.c

To put it short, a valid session id may consists of digits, letters A to Z (both upper and lower case), comma and dash. Described as a character class, it would be [-,a-zA-Z0-9]. A valid session id may have the length between 1 and 128 characters. To validate session ids, the easiest way to do it use a function like:

<?php

function session_valid_id($session_id)
{
    return preg_match('/^[-,a-zA-Z0-9]{1,128}$/', $session_id) > 0;
}

?>

session_id() itself will happily accept invalid session ids, but if you try to start a session using an invalid id, you will get the following error:

Warning: session_start(): The session id is too long or contains illegal characters, valid characters are a-z, A-Z, 0-9 and '-,'